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Single-crystal reflection and Raman spectra of the polydiacetylene THD

✍ Scribed by M.E. Morrow; K.M. White; C.J. Eckhardt; D.J. Sandman

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 572 KB
Volume: 140
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80454-2

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✦ Synopsis

The 298 K Raman and reflection spectra of the polydiacetylene THD, a close structural variant of DCHD, are presented. The polymer double-and triple-bond stretch frequencies are 1485 and 21 I 1 cm-', respectively, and the lowest electronic transition peaks at 17600 cm-'. The reflection spectrum is more reminiscent of the polydiacetylene TCDU than DCHD.

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