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Single-crystal endor on bis-(diethyl-dithiocarbamato)Cu(II): bis-(diethyl-dithiocarbamato)Zn(II)

✍ Scribed by R. Kirmse; J. Stach; R. Böttcher


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
289 KB
Volume
75
Category
Article
ISSN
0009-2614

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✦ Synopsis


An rnvest~~tion of the 'H ENDOR spectra of Cu<ct2dtc)z subsntuted unto single crystals of Zn(ctZdtc)Z is reported. The symmetry of the CuZnSa umt rcsultmg upon incorporation of the Cu complex m the Zn host appears to be consrderably drfferent from the ZnzSs unit in pure Zn(etzdtc)z. Contnbuttons to the ESR hnewldth and the occurrence of spuAhp tines zue dwzusscd. * Presented III part at the Chemtedozententagung der Chemlschen GeseUschaft der DDR, Freiberg. 28-30 Aped 1979.


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✍ R. Kirmse; U. Abram; R. Böttcher 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 304 KB

The 13C znd 14N ENDOR spccka ofC~(et~dtc)~ subsMuted into single cry&s of Ni(etzdt& are reported. 'The WItrosymmetic, PLUMI shctue of the host molecule has been retained by the guest. Comparison between the 13C ENDOR data obtamed for Cu/Ni[et2dtc)z and Cu/Zn(etldtc):, hu been made considering the di