Electrochemical behavior of the water-soluble C,,-y-CD (1:2) inclusion complex has been studied on the hanging mercury drop electrode. A one-electron reversible adsorptive electro-reduction and three irreversible adsorptive electro-reductions were detected by cyclic voltammetry. The amount of &,-y-C
Single and double reduction of C60 in 2:1 γ-cyclodextrin/[60]fullerene inclusion complexes by cyclodextrin radicals
✍ Scribed by Annamaria Quaranta; Yongmin Zhang; Yali Wang; Ruth Edge; Suppiah Navaratnam; Edward J. Land; René V. Bensasson
- Book ID
- 108089088
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 246 KB
- Volume
- 354
- Category
- Article
- ISSN
- 0301-0104
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📜 SIMILAR VOLUMES
Highly selective generation of the supramolecular C 60 1-and C 60 2-species from γ-cyclodextrin-bicapped C 60 in DMSO has been achieved for the first time even in the presence of oxygen by using a large excess of NaH and excess NaBH 4 , respectively.
The excitation of CW incorporated in Won X-100 micelles has been studied by laser flash photolysis. Reductive quenching of triplet-excited 'Cso by diazabicyclooctane (DABCO) has been established in the micellar assembly, in aqueous solution of the fullerene embedded in y-cyclodextrin, in alcohols an