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SINDO1 study of the photoisomerization of 2-cyanopyrrole to 3-cyanopyrrole

✍ Scribed by Behrens, Sabine; Jug, Karl


Book ID
126145721
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
872 KB
Volume
55
Category
Article
ISSN
0022-3263

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The reductive coupling of 2-cyanopyrrole
✍ Christian BrΓΌckner; Lily Y. Xie; David Dolphin πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 776 KB

2-Cyanopyrrole was found to form (2-pyrrolyhnetheoe)-(2-pyxmlyhnethyl)imine when treated witi lithium ahuninum hydride (LAH). followed by a mild work-up. A plausible mechanism of this reductive coupling was inferred from a series of experiments, including ~~AI-NMR, deuteration experiments, and the r