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[SiNb12O40]16− and [GeNb12O40]16−: Highly Charged Keggin Ions with Sticky Surfaces

✍ Scribed by May Nyman; François Bonhomme; Todd M. Alam; John B. Parise; Gavin M. B. Vaughan

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
190 KB
Volume
43
Category
Article
ISSN
0044-8249

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[ε-PMo12O36(OH)4{La(H2O)4}4]5+: The Firs
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Polyoxometalates, often considered as soluble metal oxides, have long attracted interest because of their large field of applications, especially in the domain of heterogeneous catalysis. [1] The famous Keggin ion [a-PMo 12 O 40 ] 3À was isolated nearly 200 years ago. Isomerization formally results