The fluorescence of dysprosium, europium and terbium was enhanced by three to four orders of magnitude when these lanthanides were excited in the presence of sodium benzoate, trioctylphosphine oxide and Triton X-100 in aqueous solutions at pH = 5.5. In all instances the excitation wavelength was ca.
โฆ LIBER โฆ
Simultaneous spectrofluorimetric determination of terbium, samarium and europium with hexafluoroacetylacetone-trioctylphosphine oxide and Triton X-100
โ Scribed by Guiyun Zhu; Zhikun Si; Jinghe Yang; Jiu Ding
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 211 KB
- Volume
- 231
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
In aqueous solution, the fluorescence mtenslty 1s a hnear function of concentration m the ranges 1 0 X 10d4-1 0 X 1 0m6 M Sm and 1 0 x 10-6-1.0
X lo-' M Tb and Eu The optimum condltlons are 1 x 10m3 M hexafluoroacetylacetone, 1 X 10m4 M tnoctylphosphme oxide and 0.05% Tnton X-100 at pH 3 0
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