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Simultaneous regioselective protection of phenyl 1-thioglucosides at the C-3 and C-6 or at the C-2 and C-6 hydroxy groups

✍ Scribed by Yasunori Ikeda; Ken Furukawa; Hidetoshi Yamada


Book ID
108309379
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
87 KB
Volume
337
Category
Article
ISSN
0008-6215

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## Abstract Two series of new compounds with sterically shielded, sp^2^‐hybridized C‐α atoms are prepared from bromo(chloro)‐2,6‐diisopropylbenzene. The α‐(2,6‐diisopropylphenyl) substituent common to all of them is used as an NMR‐spectroscopic indicator for the ease of aryl‐α single‐bond rotation.