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Simultaneous long-chain branching and random scission: I. Monte Carlo simulation

✍ Scribed by Hidetaka Tobita

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 254 KB
Volume: 39
Category: Article
ISSN: 0887-6266
DOI: 10.1002/1099-0488(20010115)39:4<391::aid-polb1011>3.0.co;2-3

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📜 SIMILAR VOLUMES

Molecular Weight Development during Simu

Molecular Weight Development during Simultaneous Chain Scission, Long-Chain Branching and Crosslinking, 1

✍ Hidetaka Tobita 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB

## Abstract A general matrix formula is proposed for the weight‐average molecular weights of the polymer systems formed through simultaneous scission, branching and crosslinking of __N__ types of chains, assuming the chain connection statistics are Markovian. For the polymerization systems in which

Molecular Weight Development during Simu

Molecular Weight Development during Simultaneous Chain Scission, Long-Chain Branching and Crosslinking, 2

✍ Hidetaka Tobita 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB

## Abstract The matrix formula developed in Part 1 of this series is applied to describe the molecular weight development during free‐radical (co)polymerization. All of the required probabilistic parameters are expressed in terms of the kinetic rate constants and pertinent concentrations. In free‐r

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Simultaneous long-chain branching and random scission. II. Analytic expression for the weight-average molecular weights

✍ Hidetaka Tobita 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB

Monte Carlo Simulation of Long-Chain Bra

Monte Carlo Simulation of Long-Chain Branched Polyethylene Chains Synthesized with Dual-Site-Type Catalyst Systems

✍ Daryoosh Beigzadeh 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 148 KB

## Abstract A Monte Carlo model for the polymerization of ethylene with long‐chain branch formation using dual‐site catalyst systems was developed. It was shown that, unlike single‐site catalyst systems, a detailed knowledge of the specifics of catalyst sites and reactor conditions is essential to

Polyethylene Made with Combinations of S

Polyethylene Made with Combinations of Single-Site-Type Catalysts: Monte Carlo Simulation of Long-Chain Branch Formation

✍ Leonardo C. Simon; Joao B. P. Soares 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 532 KB

Random End-Switching Configurational Bia

Random End-Switching Configurational Bias Monte Carlo for Long Chain Molecules

✍ Emmanuel Karaiskos; Jason deJoannis; Spiros H. Anastasiadis; Ioannis A. Bitsanis 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB

## Abstract **Summary:** The exponential attrition of configurational bias Monte Carlo for long chains can be reduced to almost quadratic by a simple modification of the basic move. Each trial move begins on the side of the remaining sub chain opposite to the cut location. This type of move is akin