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Simultaneous HPLC determination of phenylurea herbicides and their corresponding anilines in water after on-line preconcentration

✍ Scribed by Hatrík, Štefan ;Lehotay, Jozef ;Tekel', Jozef


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
292 KB
Volume
17
Category
Article
ISSN
0935-6304

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✦ Synopsis


Abstract

On‐line preconcentration on a short C~18~ column, prior to HPLC with UV and electrochemical detection, has been used for determination of some phenylurea herbicides and their possible degradation products, substituted anilines, in water samples. With electrochemical detection the detection limit at a signal‐to‐noise ratio of 3 was 5 ppt for 4‐chloroaniline and 4‐bromoaniline and 7 ppt for 3,4‐dichloroaniline; with UV detection the detection limit was ca 300 ppt for all analytes.