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Simultaneous Determination of Ascorbic Acid and Uric Acid by Using a PVC/TTF-TCNQ Composite Electrode as Detector in a FIA System

✍ Scribed by Manuel Cano; Beatriz Palenzuela; J. Luis Ávila; Rafael Rodríguez-Amaro


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
107 KB
Volume
19
Category
Article
ISSN
1040-0397

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✦ Synopsis


Abstract

A PVC/TTF‐TCNQ composite electrode has been employed as detector in a flow injection system. The proposed method allows the simultaneous detection of ascorbic acid (AA) and uric acid (UA) in mixtures by using a FIA system in a simple manner, without pre‐treatment or modified electrode. This method is based on the amperometric determination of (a) ascorbic acid at 0.15 V and (b) both analytes at 0.35 V, being the response linear in the range 1×10^−2^–4×10^−4^ M for both analytes with detection limits (S/N=3) of 1.2×10^−4^ M and 8.1×10^−5^ M for AA and UA, respectively.