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Simultaneous construction of polymer backbone and side chains by three-component polycondensation. Synthesis of polyethers with keto side chains from dialdehydes, alkylene bis(trimethylsilyl) ethers, and silyl enol ethers

✍ Scribed by Tsutomu Yokozawa; Lui Niimi; Kazuyuki Takenoya

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 770 KB
Volume: 199
Category: Article
ISSN: 1022-1352
DOI: 10.1002/(sici)1521-3935(19981101)199:11<2453::aid-macp2453>3.0.co;2-#

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Simultaneous construction of a polyether

Simultaneous construction of a polyether backbone and a variety of keto side chains by three-component polycondensation: An improved method for the use of a variety of silyl enol ethers

✍ Tsutomu Yokozawa; Lui Niimi 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 204 KB 👁 2 views

For the synthesis of polyethers with a variety of keto side chains in a one-step reaction, the three-component polycondensation of dialdehydes, diol disilyl ethers, and silyl enol ethers of ketones was investigated. The method of monomer addition strongly affected the molecular weight of polymers an