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Simultaneous absorption and reaction of two gases in a liquid/formation of ethyl chloride from ethylene and hydrogen chloride

✍ Scribed by Raghunath V. Chaudhari; L.K. Doraiswamy

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 456 KB
Volume: 29
Category: Article
ISSN: 0009-2509
DOI: 10.1016/0009-2509(74)80043-6

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✦ Synopsis

The simultaneous absorption of ethylene and hydrogen chloride with chemical reaction in a medium of nitrobenzene containing dissolved catalyst (aluminium chloride) was studied. The experimental results indicated that the absorption occurs in the kinetic regime. The reaction was found to be first-order with respect to the reactants (ethylene and hydrogen chloride) as well as the catalyst. The rate constants calculated were 1.16 x lo', 2.80 x lo', 6.11 x 10' and 144 x lo6 [cm'/g mole]*/sec at 30,40, 50 and 60°C respectively and the activation energy 16600 Cal/g mole.

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