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Simulation and Modelling of Thin Film ϕ(ρz) Curves for Electron Probe Microanalysis

✍ Scribed by A. Chan; J. D. Brown


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
838 KB
Volume
26
Category
Article
ISSN
0049-8246

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✦ Synopsis


A method is described for calculating thin Ðlm /(qz) curves from the corresponding bulk /(qz) curves. A multiple scattering Monte Carlo program was used to simulate more than 300 thin Ðlm /(qz) curves with di †erent Ðlmsubstrate combinations. The simulations were made at normal electron incidence in the energy range 10-30 keV. From these data, a general expression was derived to predict thin Ðlm /(qz) curves for any Ðlm-substrate combination at any electron energy for EPMA. Calculated k-ratios were compared with existing measured k-ratios in order to conÐrm the validity of the model.


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A new bulk matrix correction program for quantitative electron probe microanalysis based on a double Gaussian u(qz) approach is presented. The independent input parameters for this new model are a (decay rate in the righthand Gaussian), surface ionization u(0), peak position and integral of u(qz) (F