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Simulate methylation reaction of arsenic(III) with methyl iodide in an aquatic system

✍ Scribed by Baowei Chen; Thanh Wang; Bin He; Chungang Yuan; Erle Gao; Guibin Jiang


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
161 KB
Volume
20
Category
Article
ISSN
0268-2605

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o