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Simplified Free-Radical Reaction Kinetics for p-Xylene Oxidation to Terephthalic Acid

✍ Scribed by W. Sun; Y. Pan; L. Zhao; X. Zhou

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
287 KB
Volume
31
Category
Article
ISSN
0930-7516

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A lumped kinetic model for liquid-phase
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lumped kinetic scheme for the liquid-phase oxidation of p-xylene to terephthalic acid catalyzed by cobalt naphthenate is developed. It is assumed that all the reactions are. zeroth-and first-order with respect to gaseous and liquid reactants, respectively. The reliability of the developed kinetic mo

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## Abstract A detailed radical chain elementary reaction mechanism for the liquid‐phase catalytic oxidation of meta‐xylene to meta‐phthalic acid catalyzed by cobalt acetate and manganese acetate and promoted by hydrogen bromide was proposed. Using several reasonable assumptions a simple fractional‐