Simplifications of the Poisson–Boltzmann Equation for the Electrostatic Interaction of Close Hydrophilic Surfaces in Water

✍ Scribed by P.Maarten Biesheuvel

• Publisher: Elsevier Science
• Year: 2001
• Tongue: English
• Weight: 95 KB
• Volume: 238
• Category: Article
• ISSN: 0021-9797
• DOI: 10.1006/jcis.2001.7515

✦ Synopsis

Simple solutions of the Poisson-Boltzmann (PB) equation for the electrostatic double-layer interaction of close, planar hydrophilic surfaces in water are evaluated. Four routes, being the weak overlap approximation, the Debye-H ückel linearization based on low electrostatic potentials, the Ettelaie-Buscall linearization based on small variations in the potential, and a new approach based on the fact that concentrations are virtually constant in the gap between close surfaces, are discussed. The Ettelaie-Buscall and constantconcentration approach become increasingly accurate for closer surfaces and are exact for touching surfaces, while the weak overlap approximation is exact for an isolated surface. The Debye-H ückel linearization is valid as long as potentials remain low, independent of separation. In contrast to the Ettelaie-Buscall approach and the weak overlap approximation, the Debye-H ückel linearization and constant-concentration approach can also be used for systems containing multivalent ions. Simulations in which the four approaches are compared with the PB equation for the constant-charge model, the constant-potential model, as being used in the DLVO theory, and the charge-regulation model are presented.