Simplex method for the computation of analytical parameters of potentiometric sensors

✍ Scribed by Robert Koncki; Stanisa̵w Ga̵b; Adam Hulanicki

• Book ID: 102982844
• Publisher: Elsevier Science
• Year: 1993
• Tongue: English
• Weight: 546 KB
• Volume: 273
• Category: Article
• ISSN: 0003-2670
• DOI: 10.1016/0003-2670(93)80193-o

✦ Synopsis

The snnplex method 1s proposed for obtammg cabbratlon parameters for potentiometruz sensors As examples an ion-selectwe electrode, an enzyme substrate electrode, a tissue electrode and a pH-enzyme electrode were chosen The effectweness of the method was checked on real expenmental data of the different sensors % procedure shows good convergence and precslon It LS esmally recommended when the classrcal least-squares method cannot be used because of non-hneanty and non-exphc@ of theoretlcal functions