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Simple theory of the charge transfer rate in ion/molecule reactions. Part 1. Derivation of the theory

✍ Scribed by Jan Turulski; Jan Niedzielski; W. Stiller


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
870 KB
Volume
79
Category
Article
ISSN
0168-1176

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Electron transfer rates in the levich an
✍ W. Schmickler; W. Vielstich πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 489 KB

The Levich and Dogonadze theory of redox reactions in solutions is regarded as a suitable model to discuss the nature of quantumeffects in electron transfer. In Section I the quantum mechanical framework-first order perturbation theory and the Born-Oppenheimer approximation-is reviewed; an inaccurac