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Simple synthesis of calix[4]arenes in a 1,2-alternate conformation

✍ Scribed by Lhoták, Pavel; Bílá, Alexandra; Budka, Jan; Pojarová, Michaela; Stibor, Ivan

Book ID
120078754
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
716 KB
Volume
14
Category
Article
ISSN
1359-7345

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✍ Arturo Arduini; Laura Domiano; Andrea Pochini; Andrea Secchi; Rocco Ungaro; Fran 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 505 KB

New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.