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Simple synthesis of 6-methyl-, 3-dimethyl-, 3-methyl-, and 3,7,8-trimethylalloxazine.

✍ Scribed by Danuta Panek-Janc; Jacek Kozioł

Book ID
104237908
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
125 KB
Volume
20
Category
Article
ISSN
0040-4039

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## Abstract The selective tritiation of methyl 10(R/S)‐hydroxy‐11(R),12(S)‐epoxyeicosa‐5,8,14‐triynoate into two C^10^‐epimeric [^3^H~6~]‐hepoxilins B~3~ methyl esters is described. These compounds are subsequently converted into two C^8^‐epimeric [^3^H~6~]‐hepoxilins A~3~ methyl esters by allylic