✦ LIBER ✦

Simple relationship between the Kirkwood-Buff parameters and the fluctuations in the particle number and concentration obtained by small-angle X-ray scattering: Application to tert-butyl alcohol and water mixtures

✍ Scribed by Keiko Nishikawa

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 372 KB
Volume: 132
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80692-3

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✦ Synopsis

By the use of the Bhatia and Thornton formulation for the scattering intensity of a two-component system, formulas are derived which connect the Kirkwood-Buff parameters with the fluctuations obtained from zero-angle X-ray scattering intensities, isothermal compressibilities and partial molar volumes. Using these formulas the Kirkwood-Buff parameters of TBA-water mixtures are obtained.