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Simple phosphorus-31 NMR method for the determination of enantiomeric purity of alcohols not requiring any chiral auxiliary compounds

✍ Scribed by Feringa, Ben L.; Smaardijk, Ab; Wynberg, Hans


Book ID
118146919
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
267 KB
Volume
107
Category
Article
ISSN
0002-7863

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An efficient chiral phosphorus derivatiz
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## Abstract The chiral phosphorus derivatizing agent (CDA) 1 was prepared from optically pure (S)‐__1,1‐bis‐2‐naphthol__. It was first used in the determination of the enantiomeric excess of chiral alcohols and amines by means of ^31^P NMR spectroscopy. It showed that, for the chiral aromatic alcoh