We consider degassing of cylindrical sample containing dissolved hydrogen. The experiment is made by the thermodesorption method. In the corresponding boundary-value problem with nonlinear dynamic boundary conditions physicalechemical processes in the bulk and on the metal surface are taken into acc
Simple model for the desorption of hydrogen from Ni surfaces
โ Scribed by George Comsa; Rudolf David
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 444 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A model is presented which describes features of the "hot", non-cosine and non-maxwelLian velocity distriiutions of Hz molecules desorbing from Ni surfaces. The model, based on detailed balancing, assumes that incident molecules encounter an activation barrier with holes. The model also correlates with results of kinetic measurements: sticking coefficient =0-l, non-activated adsorption at low temperatures and activated adsorption at high temperatures.
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