Simple, Efficient and Distribution-free Approach to Interaction Effects in Complex Structural Equation Models

A theoretical approach to substituent ef

A theoretical approach to substituent effects. Structural consequences of electrostatic and orbital interactions in model mono- and disubstituted methanes

✍ Addy Pross; Leo Radom 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 491 KB

## Abstract __Ab initio__ molecular orbital theory is used to examine the effect of substituents on bond lengths in mono‐ and disubstituted methanes. The relative importance of electrostatic and orbital interaction terms are assessed. The results suggest that for substituents (X) which show powerfu