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Simple dinuclear iron complexes as catalysts for alkane oxidation

✍ Scribed by M. Fontecave; S. Ménage; J.M. Vincent; C. Lambeaux

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
55 KB
Volume
59
Category
Article
ISSN
0162-0134

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Hydroxylation of Alkanes by Molecular Oxygen with Dinuclear Fe(II) Macrocyclic Complexes as Catalysts. -The 24-membered macrocyclic iron complex, RBP, is found to be a better catalyst for the oxidation of alkanes (I) and (IV) than the 30-membered macrocycle RBB. H 2 S acts as 2-electron reductant. -