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Simple dichlorotris(triphenylphosphine)ruthenium-catalyzed synthesis of the 3,5,6,7-tetrahydro-4(2H)-benzofuranone system

✍ Scribed by Albin, Pnina; Blum, Jochanan; Dunkelblum, Esra; Sasson, Yoel

Book ID
126901588
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
287 KB
Volume
40
Category
Article
ISSN
0022-3263

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Synthesis and chemical transformation of
Synthesis and chemical transformation of fused tetrazoles derived from 2-bromomethyl- and 2-iodomethyl-3,5,6,7-tetrahydro-4(2H)-benzofuranones
✍ Malose J. Mphahlele; Thwanthwadi B. Moekwa πŸ“‚ Article πŸ“… 2006 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 132 KB

## Abstract magnified image The 2‐bromomethyl‐3,5,6,7‐tetrahydrobenzofuranones **1a‐d** were subjected to triazidochlorosilanesodium azide‐mediated Schmidt rearrangement to afford the corresponding tetrazolofuroazepine derivatives **2a‐d** __via__ methylene shift. Under similar reaction conditions