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Simple and Efficient 1,3-Isomerization of Allylic Alcohols using a Supported Monomeric Vanadium-Oxide Catalyst

✍ Scribed by Mitsudome, Takato; Sueoka, Shoichiro; Ikeda, Satoshi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi


Book ID
120446671
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
332 KB
Volume
5
Category
Article
ISSN
1867-3880

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A new catalyst system of [RuCl 2 (p-cymene)] 2 /Cs 2 CO 3 has been disclosed for highly efficient aerobic oxidation of activated alcohols to the corresponding carbonyl compounds, which is characterized by its high selectivity and activity, operational simplicity, and low air and moisture sensitivity