Silylstannylation of Allenes and Silylstannylation—Cyclization of Allenynes. Synthesis of Highly Functionalized Allylstannanes and Carbocyclic and Heterocyclic Compounds.
✍ Scribed by Ramaiah Kumareswaran; Seunghoon Shin; Isabelle Gallou; T. V. RajanBabu
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 46 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Anions of 1-halo-4-hexenyl phosphonamides derived from chiral, enantiopure C2 symmetrical 1,2-diamino cyclohexane react at the gamma-position in conjugate addition reactions with alpha, beta-unsaturated carbonyl compounds such as cyclopentenone, 4-(H)-furanone, pyrroline-2-one, and cinnamates to giv
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