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(Silylgermyl)methyl and (germylsilyl)methyl chemistry. Synthesis and rearrangements of LMCH2GeMe2SiMe3 and LMCH2SiMe2GeMe3 [LM = (.eta.5-C5H5)M(CO)n; M = iron (n = 2), tungsten (n = 3)]

โœ Scribed by Sharma, Sneh; Pannell, Keith H.


Book ID
127145614
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
581 KB
Volume
12
Category
Article
ISSN
0276-7333

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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit