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Silylation of Cellulose with Hexamethyldisilazane in Liquid AmmoniaFirst Examples of Completely Trimethylsilylated Cellulose

✍ Scribed by Mormann, Werner; Demeter, Jürgen

Book ID
127053441
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
68 KB
Volume
32
Category
Article
ISSN
0024-9297

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📜 SIMILAR VOLUMES

Silylation of cellulose and low-molecula
Silylation of cellulose and low-molecular-weight carbohydrates with hexamethyldisilazane in liquid ammonia
✍ Werner Mormann; Thomas Wagner 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB

## Abstract Silylation of cellulose and some low‐molecular‐weight hydroxy compounds (1,2‐propanediol, D‐glucose, methyl α‐D‐glucoside, sucrose and β‐cyclodextrin) has been performed with hexamethyldisilazane (HMDS) in liquid ammonia at elevated temperature in an autoclave. No salt‐like by‐products

Trimethylsilylation of Cellulose in Ioni
Trimethylsilylation of Cellulose in Ionic Liquids
✍ Werner Mormann; Markus Wezstein 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB

## Abstract Trimethylsilylation of cellulose in different 1,3‐dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a degree of substitution (DS) greater than 1 is insoluble in the IL. The maximum DS obtai