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Silyl thioacetals: Versatile building blocks for organic synthesis

✍ Scribed by Ernst Schaumann

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 488 KB
Volume: 18
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.20344

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✦ Synopsis

Abstract

Silyl thioacetals have been shown to allow entry into the chemistry of silyl(arythio) carbenes. Moreover, silyl thioacetals are successful reaction components in the homo‐Peterson cyclopropane synthesis, and, via 1,4‐silyl migration, in the domino synthesis of larger carbocyclic and of heterocyclic rings. Finally, the application of thioacetal‐based silyl migration in the synthesis of acyclic systems is discussed. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:600–608, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20344

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