Silyl-substituted cyclopropyl carbenoids
β Scribed by Xavier Creary; Ziqi Jiang; Mark Butchko; Kathy McLean
- Book ID
- 103404301
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 134 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The synthesis of the cyclopropyl silyl ketones 1 4 is described. The trimethylsilyl ketone 1 was prepared from geraniol ((E)-5) in ca. 10% overall yield by cyclopropanation leading to 6 , Cr03 oxidation to the aldehyde 8, reaction of the latter with trimethylsilyl anion to 14A + B, and CrO? oxidatio
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