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Silyl phosphites. 8. Deoxygenation reactions by means of tris(trimethylsilyl) phosphite

✍ Scribed by Mitsuo Sekine; Hikaru Yamagata; Tsujiaki Hata

Book ID
108384721
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
245 KB
Volume
20
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Reactions of fluorinated hydroxy and epo
Reactions of fluorinated hydroxy and epoxy ketones with tris(trimethylsilyl) phosphite
✍ Vitalij G. Ratner; Enno Lork; Kazimir I. Pashkevich; Gerd-Volker RΓΆschenthaler πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 172 KB πŸ‘ 2 views

## Reacting the fluoroalkyl b-trimethylsi- R‫ב‬ Me) with tris(trimethylsilyl) phosphite gave a diastereomeric mixture of ␣,c-hydroxy phosphonic acids and their derivatives. With a fluorinated b-epoxy ketone and tris(trimethylsilyl) phosphite, corresponding silyl esters and, after hydrolysis, an ␣-