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Silyl Migrations

✍ Scribed by Mitsuo Kira; Takeaki Iwamoto

Book ID
101948616
Publisher
John Wiley and Sons
Year
2003
Weight
53 KB
Volume
34
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Intermolecular Silyl Migration Reactions
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ChemInform Abstract: Silyl Group Migrati
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

The 1,4 C→O silyl migrations of various
The 1,4 C→O silyl migrations of various furan and thiophene systems
✍ Patrick G. SpinazzΓ©; Brian A. Keay πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 257 KB

2-Trialkylsilyl-3-hydroxymethyl-furans and -thiophenes undergo a 1,4 C-O silyl migration when treated with bases containing either potassium or sodium counterions to produce 3-[(trialkylsilyl)oxymethyl]furans and -thiophenes in excellent yields. We have shown that 3-[(t-butyldimethylsilyl)oxymethyl