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Silyl derivatives of steroids. Intramolecular silylation processes and electron impact-induced reciprocal exchange of trimethylsilyl groups

โœ Scribed by Vouros, Paul


Book ID
127230644
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
687 KB
Volume
38
Category
Article
ISSN
0022-3263

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The electron impact induced cleavage of
โœ Paul Vouros; D. J. Harvey ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 703 KB

The cleavage of the C-17-C-20 bond in the trimethylsilyl derivatives of C,, steroids has been investigated with the aid of isotopic labelling. A significant amount of reciprocal exchange was observed between trimethylsilyl groups or hydrogen atoms on the 20-0and 17-0-positions. The loss of positiona