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Silver−Thioether Crown Complexes as Templates for the Synthesis of Extended Polyiodide Networks: Synthesis and X-ray Crystal Structures of [Ag 2 ([15]aneS 5 ) 2 ]I 12 , [Ag([18]aneS 6 )]I 7 , [Ag([18]aneS 6 )]I 3 , and [Ag([9]aneS 3 ) 2 ]I 5†

✍ Scribed by Blake, Alexander J.; Gould, Robert O.; Li, Wan-Sheung; Lippolis, Vito; Parsons, Simon; Radek, Christian; Schröder, Martin

Book ID
126446811
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
476 KB
Volume
37
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

Thioether crown complexes as templates f
Thioether crown complexes as templates for the assembly of extended polyiodide networks: synthesis and structures of {[M([16]aneS4)]2I}I11 (M = Pd, Pt), [Pd(cis-HO)2[14]aneS4)](I3)2, [Pd([9]aneS3)2](Ix)2 (x = 3, 5)
✍ Alexander J. Blake; Robert O. Gould; Wan-Sheung Li; Vito Lippolis; Simon Parsons 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 363 KB

Pd(II) and Pt(II) complexes of [16]aneS 4 and Pd(II) complexes of cis-(HO) 2 [14]aneS 4 and [9]aneS 3 have been used as templates for the selfassembly of polyiodide ions. The complexes {[M([16]aneS 4 )] 2 I}I 11 (M ϭ Pd, Pt), [Pd(cis-(HO) 2 [14]aneS 4 )](I 3 ) 2 , [Pd([9]aneS 3 ) 2 ](I x ) 2 (x ϭ 3,