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Silver(II) Fluorosulfate: A Thermally Fragile Ferromagnetic Derivative of Divalent Silver in an Oxa-Ligand Environment

✍ Scribed by Przemysław J. Malinowski; Mariana Derzsi; Zoran Mazej; Zvonko Jagličić; Piotr J. Leszczyński; Tomasz Michałowski; Wojciech Grochala


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
638 KB
Volume
2011
Category
Article
ISSN
1434-1948

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ChemInform Abstract: Silver(II) Fluorosu
✍ Przemyslaw J. Malinowski; Mariana Derzsi; Zoran Mazej; Zvonko Jaglicic; Piotr J. 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 22 KB

Silver(II) Fluorosulfate: A Thermally Fragile Ferromagnetic Derivative of Divalent Silver in an Oxa-Ligand Environment. -Two novel routes to synthesize Ag(SO3F)2 are reported: methathesis reaction between Ag(SbF6)2 and KSO3F in anhydrous HF (-84→+25 °C; ≈100% yield) and reaction of AgF2 with HSO3F (