✦ LIBER ✦

Silver ion perturbation of olefin photochemistry

✍ Scribed by Harry Morrison; Carol Koviak

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 194 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84623-7

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✦ Synopsis

AI(I) catalysis and inhibition of alkene E/Z photoisomerization. and its effect on tetramethylethylene photochemistry, are reported. The catalysis of organic photochemical reactions by metal ions has been a subject of considerable recent interestl, prompted in part by the possible use of metal complexation as a means of smplifying light absorption in otherwise relatively transparent chromophores (as. for example, in potentially useful solar energy storage systemsj2. Transition metals form relatively strong complexes with the otherwise weakly absorbing alkenes3 and the For recent reviews, see (a) R.G.

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