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Silver-Catalyzed Rearrangement of Propargylic Sulfinates to Allenic Sulfones

✍ Scribed by Michael Harmata; Chaofeng Huang

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 111 KB
Volume: 350
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200700447

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✦ Synopsis

Abstract

Treatment of propargylic sulfinate esters with 2 mol % of silver hexafluoroantimonate results in the rapid formation of allenic sulfones in essentially quantitative yield.

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