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Silicon nanowires as negative electrode for lithium-ion microbatteries

✍ Scribed by Barbara Laïk; Laurent Eude; Jean-Pierre Pereira-Ramos; Costel Sorin Cojocaru; Didier Pribat; Emmanuelle Rouvière


Book ID
108119221
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
865 KB
Volume
53
Category
Article
ISSN
0013-4686

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MnVzO,, (0.5 < 6 < 1) amorphous oxides reversibly insert large amounts of Li (e.g. Li12MnV206,96) at low voltage (= 1 V). During the first Li insertion, Mn 4+ is first reduced to Mnz+ and Vs' is reduced to V3+. Upon further cycling, the V oxidation state varies reversibly between +3 and +5, whereas