𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Techniques for Preparative Silylations-Desilylations

✍ Scribed by Vorbrüggen, Helmut

Book ID
118220938
Publisher
Wiley
Year
2004
Tongue
German
Weight
271 KB
Edition
1
Category
Article
ISBN
3527306684

No coin nor oath required. For personal study only.

✦ Synopsis

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis.
Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods.
The compact form and clear structure of this monograph make this a long-awaited ready reference.

From the contents:

Introduction
* Techniques of Preparative Silylations-Desilylations
* Preparation and Properties of Siliconoxy-Leaving Groups
* Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide
* Reactions of Aldehydes and Ketones
* Reactions of Alcohols, Ethers and Epoxides
* Reaction of N-O Systems
* Reactions of S-O and Se-O Systems
* Cyclizations and Ring Enlargements
* Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions
* Formation of Carbon-Phosphorous Double- and Triple Bonds
* Reductions and Oxidations
* Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds
* Formation of Polymers

📜 SIMILAR VOLUMES

Silicon-Mediated Transformations of Func
Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Preparation and Properties of Silyloxy Leaving Groups
✍ Vorbrüggen, Helmut 📂 Article 📅 2004 🏛 Wiley 🌐 German ⚖ 200 KB

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of sily

Silicon-Mediated Transformations of Func
Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Formation of Organic and Inorganic Polymers
✍ Vorbrüggen, Helmut 📂 Article 📅 2004 🏛 Wiley 🌐 German ⚖ 153 KB

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of sily

Silicon-Mediated Transformations of Func
Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Formation of Carbon-Phosphorus Double Bonds
✍ Vorbrüggen, Helmut 📂 Article 📅 2004 🏛 Wiley 🌐 German ⚖ 161 KB

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of sily

Silicon-Mediated Transformations of Func
Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Reactions of Alcohols, Esters, Silyl Ethers, Epoxides, and Haloalkanes
✍ Vorbrüggen, Helmut 📂 Article 📅 2004 🏛 Wiley 🌐 German ⚖ 255 KB

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of sily

Silicon-Mediated Transformations of Func
Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Reactions of S-O and Se-O Systems
✍ Vorbrüggen, Helmut 📂 Article 📅 2004 🏛 Wiley 🌐 German ⚖ 622 KB

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of sily

Silicon-Mediated Transformations of Func
Silicon-Mediated Transformations of Functional Groups (VORBRUEGGEN:SILOXY O-BK) || Dehydration - Halogenation - Activation and Silylation of Inorganic and Organic Salts and Metallorganic Compounds
✍ Vorbrüggen, Helmut 📂 Article 📅 2004 🏛 Wiley 🌐 German ⚖ 440 KB

In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of sily