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Silicon-Mediated Synthesis of Selenoaldehydes and Selenoacylsilanes and Their Hetero Diels–Alder Reactions

✍ Scribed by Degl'Innocenti, Alessandro; Capperucci, Antonella; Acciai, Miriam; Tiberi, Caterina

Book ID
127088937
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
278 KB
Volume
184
Category
Article
ISSN
1042-6507

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✍ Tietze, Lutz F. ;Meier, Heinrich ;Nutt, Heinrich 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 875 KB

## Abstract The tandem Knoevenagel hetero Diels‐Alder reaction of 4,4,4‐trichloro‐3‐oxobutanal (4), the malondialdehyde derivative 11a, and the enol ether 13 was followed by separation of the diastereomers and treatment with DBU in methanol. Thermolysis in xylene then gave the secologanin derivativ