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Silicon in organosulphur chemistry. Part 2. Synthesis of unsymmetrical disulphides

✍ Scribed by Giuseppe Capozzi; Antonella Capperucci; Alessandro Degl'Innocenti; Rosa Del Duce; Stefano Menichetti

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 211 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99178-0

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The reaction of bis(trimethylsilyl)sulphide with thiosulphinates and thiosulphonates in an inert solvent under neutral and mild conditions gives symmetrical alkyl-or aryl-trisulphides. Little attention has been devoted to the synthesis of organic trisulphides, although this class of compounds seems

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