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Silicon in benzamide directed ortho metalation reactions. Carbo- and bromo-desilylations and synthesis of naturally-occurring anthraquinones

โœ Scribed by R.J. Mills; V. Snieckus


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
201 KB
Volume
25
Category
Article
ISSN
0040-4039

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Silicon in benzamide directed ortho meta
โœ R.J. Mills; V. Snieckus ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 181 KB

The n,a-bis(trimethylsilvl)-o-toluamides 4 and 2, systems protected from benz.ylic deprotonation, are available startinq iiiaterials for%the short syntheses of peri-methyl substituted benz[a]anthraquinones $,a\_ respectively. and 3 and desoxverythrolaccin trimethyl ether ,I$, The recent demonstratio