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Silicon-directed carbon-carbon bond cleavage in the removal of angular substituents on octalins

✍ Scribed by Furth, Paul S.; Hwu, Jih Ru


Book ID
118038095
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
370 KB
Volume
54
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Carbon silicon bond cleavage in the oxid
✍ Enrico Baciocchi; Tiziana Del Giacco; Cesare Rol; Giovanni Vittorio Sebastiani πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 234 KB

Benzyltrirrethylsilanes react with cerium(IV) ammonium nitrate in AcOH to give products -of C-Si cleavage (benzyl nitrate and acetate), under very mild conditions and in quantitative yields. The reaction rate is very sensitive to the nature of the ring substituents (y= -5.4), which clearly suggests