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Silicon-29 nuclear magnetic resonance studies of aqueous silicate solutions. Part 5.?First-order patterns in potassium silicate solutions enriched with silicon-29

✍ Scribed by Harris, Robin K.; Knight, Christopher T. G.


Book ID
121482220
Publisher
The Royal Society of Chemistry
Year
1983
Weight
918 KB
Volume
79
Category
Article
ISSN
0300-9238

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Silicon-29 nuclear magnetic resonance st
✍ Christopher T. G. Knight; Robin K. Harris πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 421 KB

The 29Si spin-lattice relaxation times, &(%), of the various silicate anions present in high-purity alkaline silicate solutions are reported. Regular silicate cages display the longest T,(29Si) values and, in the case of the cubic octamenc cage, an unexpectedly large nuclear Overhauser enhancement,