𝔖 Bobbio Scriptorium
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Silica-Protected Micron and Sub-Micron Capsules and Particles for Self-Healing at the Microscale

✍ Scribed by Aaron C. Jackson; Jonathan A. Bartelt; Kamil Marczewski; Nancy R. Sottos; Paul V. Braun


Book ID
102944363
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
560 KB
Volume
32
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

A generalized silica coating scheme is used to functionalize and protect sub‐micron and micron size dicyclopentadiene monomer‐filled capsules and polymer‐protected Grubbs' catalyst particles. These capsules and particles are used for self‐healing of microscale damage in an epoxy‐based polymer. The silica layer both protects the capsules and particles, and limits their aggregation when added to an epoxy matrix, enabling the capsules and particles to be dispersed at high concentrations with little loss of reactivity. magnified image