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Silica gel-assisted reduction of nitrostyrenes to 2-aryl-1-nitroalkanes with sodium borohydride

✍ Scribed by Achintya K. Sinhababu; Ronald T. Borchardt


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
256 KB
Volume
24
Category
Article
ISSN
0040-4039

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Silica gel-assisted reduction of nitrost
✍ Achintya K. Sinhababu; Ronald T. Borchardt πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 French βš– 263 KB

## Abstract Reduction of nitrostyrenes with sodium borodeuteride in the presence of silica gel (70‐270 mesh) in a mixture of chloroform and 2‐propanol gave the corresponding deuterated nitroethanes in near quantitative yields, free of dimeric products with 72‐81% deuterium incorporation. The method