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Silaphenylmercuric Triflate Catalyzed Reactions: Synthesis of a Solid-Supported Mercuric Salt Catalyst

✍ Scribed by Hirofumi Yamamoto; Ikuo Sasaki; Yuki Hirai; Kosuke Namba; Hiroshi Imagawa; Mugio Nishizawa

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 385 KB
Volume: 48
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200804641

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✦ Synopsis

Abstract

Let it flow, let it flow: A procedure to generate the first solid‐supported mercuric salt, silaphenylmercuric triflate, is described. Silaphenylmercuric triflate showed remarkable catalytic activity for an indole synthesis, furanoyne cyclization, arylyne cyclization, and tandem carbocyclizations. An efficient flow reaction system for indole synthesis and arylyne cyclization is also described (see figure).magnified image

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