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Silafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanes

✍ Scribed by Tamao, Kohei; Ishida, Neyoshi; Tanaka, Tatsu; Kumada, Makoto


Book ID
115487506
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
429 KB
Volume
2
Category
Article
ISSN
0276-7333

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Silafunctional compounds in organic synt
✍ Kohei Tamao; Makoto Kumada; Kimio Maeda 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 232 KB

The carbon-silicon bond in alkenyl(alkoxy)silanes is readily cleaved by hydrogen peroxide to form the corresponding aldehydes, carboxylic acids or ketones, depending upon the nature of the alkenyl group and the reaction conditions. We have recently reported that the silicon-carbon bond in alkyl(alk